CFD simulation of pervaporation of organic aqueous mixture through silicalite nano-pore zeolite membrane
Authors
Abstract:
Nanopore silicalite type membranes were prepared on the outer surface of a porous-mullite tube by in situ liquid phase hydrothermal synthesis. The hydrothermal crystallization was carried out under an autogenously pressure, at a static condition and temperature of 180 °C with tetrapropylammonium bromide (TPABr) as a template agent. The molar composition of the starting gel of silicalite zeolite membrane was: Na2O/SiO2=0.287-0.450, H2O/SiO2 = 8-15, TPABr/SiO2 = 0.01-0.04. The zeolites calcinations were carried out in air at 530 °C, to burn off the template (TPABr) within the zeolites. X-ray diffraction (XRD) patterns of the membranes consisted of peaks corresponding to the support and zeolite. The crystal species were characterized by XRD, and morphology of the supports subjected to crystallization was characterized by scanning electron microscopy (SEM). Performance of silicalite nanoporous membranes was studied for separation of water-unsymmetrical dimethylhydrazine (UDMH) mixtures using pervaporation (PV). Finally, a comprehensive steady state model was developed for the pervaporation of a water-UDMH mixture by COMSOL Multiphysics software version 5.2. The developed model was strongly capable of predicting the effect of various dimensional factors on concentration and velocity distribution within the membrane module. The best silicalite zeolite membranes had a water flux of 3.34 kg/m2.h at 27 °C. The best PV selectivity for Silicalite membranes obtained was 53.
similar resources
Separation of aqueous salt solution by pervaporation through hybrid organic-inorganic membrane: effect of operating conditions
Hybrid polymer-inorganic membranes were prepared by crosslinking poly(vinyl alcohol) (PVA), maleic acid (MA) and silica via an aqueous sol-gel route. Membrane characterisation results revealed silica nanoparticles (<10 nm) were well dispersed in the polymer matrix and significantly reduced swelling of the membrane. The membranes were tested for pervaporation separation of aqueous salt solution ...
full textStability Improvement of Immobilized a-amylase using Nano Pore Zeolite
Background: Enzyme engineering by immobilization techniques has proven to be well compatible with the other chemical or biological approaches aiming to improve enzyme’s functions and stability. Zeolites are porous alumino-silicates with a wide range of porosity and particle size along with the other remarkable properties such as high surface area, high stability against a wide range temperature...
full textMolecular sieving MFI-type zeolite membranes for pervaporation separation of xylene isomers.
Molecular sieving MFI-type zeolite membranes were prepared by a secondary growth method without using an organic template. Silicalite membranes with intercrystalline pores minimized or eliminated were obtained by this synthesis method which avoids the template removal step. The silicalite membrane exhibits molecular sieving characteristics with pervaporation separation factor for p-xylene to o-...
full textCFD Simulation of Mass Transfer in Membrane Evaporators for Concentration of Aqueous Solutions
Osmotic evaporation (OE) process is usually suggested to concentrate aqueous solutions. OE is a concentration technique based on the use of mesoporous or macroporous and hydrophobic membranes. The difference between the activity of solutions results in a pressure difference between the upstream diluted solution and the downstream (usually concentrated brine) solution. The latter generates a wat...
full textNovel organic–inorganic pervaporation membrane with a superhydrophobic surface for the separation of ethanol from an aqueous solution
full text
Effect of Ethylene Glycol as Pore Former on Polyphenylsulfone Hollow Fiber Membrane for Crude Palm Oil Deacidification through Membrane Contactor
In this study, polyphenylsulfone (PPSU) hollow fiber membrane was fabricated via a wet spinning method with the addition of ethylene glycol (EG) in the range of 0-10 wt% as the additive. The EG was added to improve the membrane pore formation and interconnectivity for better membrane contactor performance in extracting and removing the free fatty acid (FFA) from crude palm oil (CPO). Four diffe...
full textMy Resources
Journal title
volume 3 issue 3
pages 121- 132
publication date 2017-09-01
By following a journal you will be notified via email when a new issue of this journal is published.
Hosted on Doprax cloud platform doprax.com
copyright © 2015-2023